Adiabatic Perturbation Theory in Quantum Dynamics by Stefan Teufel

By Stefan Teufel

Separation of scales performs a basic function within the realizing of the dynamical behaviour of advanced structures in physics and different ordinary sciences. A fashionable instance is the Born-Oppenheimer approximation in molecular dynamics. This publication makes a speciality of a up to date method of adiabatic perturbation idea, which emphasizes the function of potent equations of movement and the separation of the adiabatic restrict from the semiclassical limit.

A precise advent supplies an summary of the topic and makes the later chapters obtainable additionally to readers much less conversant in the fabric. even supposing the overall mathematical idea in line with pseudodifferential calculus is gifted intimately, there's an emphasis on concrete and correct examples from physics. functions variety from molecular dynamics to the dynamics of electrons in a crystal and from the quantum mechanics of partly restrained platforms to Dirac debris and nonrelativistic QED.

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3) 2 P˙ (s) ∆(s) 2 + ˙ P¨ (s) P˙ (s) H(s) + 2 ∆(s) ∆(s) . 3 is clearly not optimal. However, it nicely displays the two mechanisms responsible for adiabatic decoupling. The size of the error depends on the size of the gap and on the variation of the eigenspaces. If either the gap is too small or the variation of the eigenspaces is too large, then adiabatic decoupling breaks down. On the other hand, if the eigenspaces are constant and only the eigenvalue varies, the subspaces decouple exactly. 3) suffices to prove the correct order of the non-adiabatic transitions near a regular eigenvalue crossing, cf.

Let G = F · (∇f )ε + adj. 8) (i) yield [ H ε , G ] = [ f ε , F ] · (∇f )ε + [ H0 , F ] · (∇f )ε + F · [ H ε , (∇f )ε ] − adj. = (∇P∗ ) P∗ · (∇f )ε − adj. + O(ε) . As in the time-adiabatic case we define A(t) = −i ε eiH ε t/ε G e−iH ε t/ε , such that ε ε ε ε t d i ε A(t) = eiH t/ε [ H ε , G ] e−iH t/ε = eiH t/ε Hod e−iH ε + O(ε) . 21) and integrate by parts, e−iH ε t/ε − e−iHdiag t/ε = ε t d A(t ) dt 0 ≤ A(t) + A(0) dt = t dt A(t ) + 0 = O(ε(1 + |t|)) . 22). 3 Time-dependent Born-Oppenheimer theory: Part I The physical background of the time-dependent Born-Oppenheimer approximation was already discussed in the Introduction.

Given a smooth and normalized family of eigenvectors χ(x) one has Re χ(x), ∇x χ(x) = 0, but, in general, Im χ(x), ∇x χ(x) = 0. In the following we distinguish two cases: Either it is possible to achieve Im χ(x), ∇x χ(x) = 0 by a smooth gauge transformation χ(x) → χ(x) = eiθ(x) χ(x) or not. 46) with domain H 2 (Rd ). Thus A acts similar to an external magnetic vector potential. However, while A comes from a connection of a line bundle over R3 , A comes from a connection of a line bundle over Rd .

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